A pH electrode measures hydrogen ion (H+) activity and generates an electrical potential or voltage. The operation of the pH electrode is based on the principle that an electric potential develops when two liquids of different pH come into contact at opposite sides of a thin glass membrane. This is a design circuit for the measurement. Amplifier U1 offsets the pH electrode by 512 mV. This is achieved using National's LM4140A-1.0 precision micro power low-dropout voltage reference, which produces an accurate 1.024 V. This voltage is divided in half to yield 512 mV using a 10 kΩ resistor divider. The output of amplifier U1, configured in a unity-gain setup, biases the reference electrode of the pH electrode with the same voltage of 512 mV at low impedance. The pH-measuring electrode produces a voltage that superimposes on this 512 mV bias voltage. Consequently, the circuit shifts the bipolar pH-electrode signal to a unipolar signal for use in a single-supply system. The second amplifier, U2, is also configured in a unity-gain configuration and buffers the output of the pH electrode. A high-input impedance buffer between the pH electrode and the measurement instrument enables the circuit to interface with a wider range of measurement instruments, including those with lower input impedance. In most applications, the output voltage of the pH electrode is sufficiently high to be used without additional amplification. If amplification is necessary, this circuit can be modified easily by adding gain resistors to U2.
The pH measurement circuit described utilizes a pH electrode, which is a specialized sensor designed to detect the activity of hydrogen ions in a solution. The electrode comprises a glass membrane that selectively interacts with H+ ions, producing a voltage proportional to the pH level of the solution. This voltage is typically bipolar, oscillating around zero volts, which poses challenges for interfacing with single-supply systems.
The design incorporates an operational amplifier (U1) configured to offset the pH signal by introducing a stable bias of 512 mV. This offset is generated using the LM4140A-1.0 voltage reference, which ensures precision and stability in the output voltage. The resistor divider network, consisting of two 10 kΩ resistors, effectively halves the reference voltage to achieve the desired offset.
The output of U1 is connected to the reference electrode of the pH sensor, allowing the sensor to operate with a bias that shifts its output range. This is critical in applications where the measurement system is powered by a single supply, as it ensures that the signal remains within the acceptable voltage range for further processing.
The second operational amplifier (U2) serves as a buffer, configured again in a unity-gain mode. This configuration is essential for maintaining high input impedance, which minimizes loading effects on the pH electrode. By buffering the output, the circuit enhances compatibility with various measurement instruments, particularly those with lower input impedance that might otherwise distort the signal.
The design allows for flexibility in applications where the output voltage from the pH electrode may need to be amplified. If required, additional gain can be introduced by integrating external resistors into the feedback loop of U2, thereby tailoring the output signal to meet specific measurement requirements.
The second amplifier U2 is set up in a unity-gain configuration and buffers the output of the pH electrode. Again, a high-input impedance buffer between the pH electrode and the measurement instrument allows the circuit to interface with a greater variety of measurement instruments including those with lower input impedance.
In most applications, the output voltage of the pH electrode is high enough to use without additional amplification. If amplification is required, this circuit can easily be modified by adding gain resistors to U2. 🔗 External reference
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